ANION COMPOSITION DETERMINATION OF NATURAL WATERS BY THE METHOD OF ION CHROMATOGRAPHIC
Abstract
An ion chromatographic method for determination of anion composition of natural waters was described. An automated 850 IC Professional, Metrohm system equipped with conductivity detector after chemical and carbon dioxide suppression was used. The main analytical characteristics were estimated for each of studied analytes. The trueness of the method was estimated by analysis of certified reference material for soft drinking water. Recovery test was performed on spiked drinking water samples. The method was applied for analysis of drinking water before and after chlorination, as well as high mountain lakes.
The selected methods were successfully applied for the analysis of water samples from high mountain lakes, as well as drinking water before and after chlorination. The results obtained in this study show that there is no indication of contamination with elements or anions in the lake water. There were no deviations found from the legally acceptable values for priority substances, which could present a risk to the aquatic environment.
About the Authors
V. Ivanova
Bulgarian Institute of Metrology, National Center of Metrology
Bulgaria
Bulgaria
Sofia
A. Surleva
University of Chemical Technology and Metallurgy
Bulgaria
Bulgaria
Sofia
References
1. B. Lopez–Ruiz. Advances in the determination of inorganic anions by ion chromatography; J. Chromatography A. 881 (2000) 607 –627
2. E. Rodriguez, S. Poynter, M. Curran, P. Haddad, R. Shellie, N. Nesterenko, B. Paull. Capillary ion chromatography with on–column focusing for ultra–trace analysis of methanesulfonate and inorganic anions in limited volume Antarctic ice core samples; Journal of Chromatography A. 1409 (2015) 182– 188
3. J.N. Stamenov, B.I. Vachev. Monitoring and management of mountain environment. Journal of Environmental Radioactivity 72 (2004) 121–128
4. G. Pekov, P. Mandjukov, S. Tsakovski, V. Simeonov. Chemical and multivariate statistical analysis of waters from the Rila mountain lake. Observatoire de mounagne de Moussala, OM2, 1998 Sofia, 253– 258 p.
5. European Commision 2014 Council Directive 98/83/EC of 3 November 1998 on the quality of water intended for human consumption, Off. J. Eur. Commun. 2014 L221, 1–101.
6. European Commission 2002 Off. J. Eur. Commun. L221 8–36
7. D. Živojinović, L. Rajaković, Application and validation of ion chromatography for the analysis of power plants water: Analysis of corrosive anions in conditioned water–steam cycles, 2011 Desalination 275 17–25
8. M. Cengiz, A. Bilgin, Determination of major sodium iodide symporter (NIS) inhibitors in drinking waters using ion chromatography with conductivity detector,2016 J. Pharm. Biomed. Analysis 120 190–197
9. D. Verrey, M. Louyer, O. Thomas, E. Baurès, Direct determination of trace–level haloacetic acids in drinking water by two–dimensional ion chromatography with suppressed conductivity, 2013 Microchemical J. 110 608–613.
10. E. Gilchrist, D. Healy, V. Morris, J. Glennon, A review of oxyhalide disinfection by–products determination inwaterby ion chromatography and ion chromatography–mass spectrometry,2016 Anal. Chim. Acta 942 12–22
11. H. Abudiak, C. Robinson, M. Duggal, S. Strafford, K. Toumba, Effect of fluoride sustained slow– releasing device on fluoride, phosphate and calcium levels in plaque biofilms over time measured using ion chromatography, 2012 J. Dentistry 40 632–638
12. I. Bajenaru, I. Minca, C. Guran, A. Josceanu, F. Bacalum, Validation of an Ion Chromatographic Method for Determinationof Anions in Wet Depositions, 2013 Rev. Chim.(Bucharest) 64 122913
13. C. Lopez–Moreno, I. Viera, A. Urbano, Validation of an ion chromatographic method for the quantification ofanions in water, 2010 Desalination 26 111–116
14. A. Krata, V. Kontozova–Deutsch, L. Bencs, F. Deutsch, R. Van Grieken, Single–run ion chromatographic separation of inorganic and low–molecular–massorganic anions under isocratic elution: Application to environmental samples, 2009 Talanta 79 16– 21.
15. Eurachem Guide: The Fitness for Purpose of Analytical Methods – A Laboratory Guide to Method.
16. V. Ivanova, A. Surleva, B. Koleva, Validation of Ion Chromatographic Method for Determination of Standard Inorganic Anions in Treated and Untreated Drinking Water, IOP Conf. Ser.: Mater. Sci. Eng. 374 (1), 2018, 012053.
17. V. Ivanova, B. Koleva, A. Surleva, Determination of pollutants in high mountain lakes by ion chromatography and inductively coupled plasma mass spectrometry, Metrology and metrological assurance 2018, 10–14 September 2018, Sozopol, Bulgaria, pp 264–267.
Review
For citations:
Ivanova V., Surleva A. ANION COMPOSITION DETERMINATION OF NATURAL WATERS BY THE METHOD OF ION CHROMATOGRAPHIC. Vestnik of M. Kozybayev North Kazakhstan University. 2019;(3 (44)):7-12.
Views:
232
Email this article 
